Enhancing the stability and porosity of penetrated metal–organic frameworks through the insertion of coordination sites† †Electronic supplementary information (ESI) available: Experimental section, crystallographic tables, IR, TG and characterization details. CCDC 1576271 and 1576272. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc04192f

Side-on coordination of boryl and borylene complexes to cationic coinage metal fragments† †Electronic supplementary information (ESI) available: Experimental; details of X-ray crystallographic and computational studies. CCDC 1033284-1033294. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc00211g

Stable porphyrin Zr and Hf metal–organic frameworks featuring 2.5 nm cages: high surface areas, SCSC transformations and catalyses† †Electronic supplementary information (ESI) available: General experimental, syntheses and characterization of the complexes mentioned in the manuscript, details of the single crystal diffraction experiments, PXRD, TG and additional figures. CCDC 1043280, 1043281, 1043914 and 1043915. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc00213c Click here for additional data file. Click here for additional data file.

State Key Laboratory of Structure Chemis Structure of Matter, Chinese Academy of S E-mail: wumy@irsm.ac.cn; wpsu@irsm.a University of Chinese Academy of Sciences, † Electronic supplementary information syntheses and characterization of the com details of the single crystal diffraction e gures. CCDC 1043280, 1043281, 10 crystallographic data in CIF or o 10.1039/c5sc00213c Cite this: Chem. Sci...

Overcoming aggregation in indium salen catalysts for isoselective lactide polymerization† †Electronic supplementary information (ESI) available: Experimental section, full characterization of compounds in solution and in the solid state, polymerization and polymer analysis, details of reactivity, tacticity determination, DSC, PGSE studies, in situ polymerization studies. CCDC 1062730–1062733 and 1062738. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc01584g Click here for additional data file. Click here for additional data file.

Switching single chain magnet behavior via photoinduced bidirectional metal-to-metal charge transfer† †Electronic supplementary information (ESI) available: Synthesis and physical measurement details. Crystal data in CIF format and additional figures (Fig. S1–S15). CCDC 1528877. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc03401f

Metal-free di- and tri-fluoromethylation of alkenes realized by visible-light-induced perylene photoredox catalysis† †Electronic supplementary information (ESI) available: Experimental details, spectral data, and crystallographic results. CCDC 1533276 and 1533274. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc01703k Click here for additional data file. Click here for additional data file.